City of Oswego Water Treatment Facility - Executive Summary

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                      Executive Summary 
 
    Watts Engineers was subcontracted by Pratt and Huth Associates, LLP to provide the 
City of Oswego a Level 3 Risk Management Program (RMP) and a Process Safety Management 
(PSM) Program in  accordance with 40 CFR 68 Risk Management Programs for Chemical 
Accidental Release Prevention and 29 CFR 1910.119 Process Safety Management for it's Water  
Treatment Facility (WTF) located at Sheldon Avenue in the City of Oswego, New York.  This 
evaluation was performed to assure that the facilities chlorine injection system complies with 
applicable regulations.  Key elements of the Risk Management Plan provided by Watts Engineers 
included:  a review of the accidental release prevention and emergency response policies; a 
review of the regulated substance handled; a worst-case and an alternative release scenario; a 
review of the general accidental release prevention program and chemical-specific prevention 
steps; a review of the five-year accident history; 
a review the emergency response program; and 
participation in meetings and planning changes to improve the Process Safety Program.   Watts 
Engineers will electronically submit this Risk Management Plan to the Environmental Protection 
Agency (EPA) by June 21, 1999.   
 
    The Oswego WTF is located on the West Side of the City of Oswego between the State 
University of New York at Oswego and the Niagara Mohawk Power Station.  It employs 
nineteen (19) full-time employees.  Activities at the facility include the treatment of water from 
Lake Ontario, clarification and filtration, and treated with chlorine gas before being released to 
the municipal water supply.   
 
    Chlorine is considered a regulated substance under the Risk Management and Process 
Safety Programs.  Characteristics of this gas or liquid include a pungent suffocating odor.  It is 
irritating to the mucous membranes.  When chlorine reacts with water, it forms hydrochloric 
acid.  Hydrochloric acid gas is a toxic and corrosiv 
e fume.  The odor threshold for chlorine is 
about 0.5 ppm.  Long term exposures to small concentrations or short term exposures to high 
concentrations may result in adverse health effects.  Since chlorine gas is heavier then air,  It can 
settle in low spots along the ground, therefore, care should be exercised while working in 
confined spaces or low lying areas.   
 
    The City of Oswego and senior management at the Water Treatment Facility have a 
strong commitment to the overall safety of it's employees, the public, and the environment.  It is 
the policy of the West Side STP to train each employee and contractor about safety 
considerations and emergency procedures in the unlikely event of a discharge.  A maximum of 
twelve thousand  (12,000) pounds of chlorine gas in six (6) tanks gas are either used or stored at 
one time at the facility.  Each tank contains two thousand (2,000) pounds of chlorine gas. The 
chlorine is composed of 99.5 percent chlorine and 0.5 percent inert ingredients 
.  The tanks are 
located on a storage pad behind the facility.  The storage pad is covered by a canopy constructed 
of sheets of corrugated steel used for a roof.  The storage area is otherwise open to air.  Chlorine 
is being delivered by truck and unloaded using a two ton crane onto a set of steel rails where the 
gas tank is stored until it is ready for use. Each end of the rails are chocked to prevent the gas 
tanks from rolling.  Each gas tank has it's own valve guard to prevent objects from coming in 
contact with the valves.   
 
 
    When a chlorine tank is needed, a two ton crane lifts the cylinder and is moved along a 
crane rail through a set of double steel doors and into the tank scale room.  The tank scale room  
is fully enclosed.  The room is labeled "chlorine hazard" and emergency instructions are posted 
at the door.  Material Safety Data Sheets (MSDS) are located in a common hallway by the 
operators station.   
 
     Next to the tank scale room is the chlorine injection r 
oom.  PVC tubing leads 
from the tanks, through the wall, and into the chlorine injection room.  Here, the chlorine is 
injected into the wastewater through a series of valves and PVC tubes. 
 
      The chlorine tanks are stored on to a calibrated scale, designed to hold the four, two 
thousand pound tanks on roller trunnions. The chlorine containers have two valves in each head, 
With the tank in a horizontal position and the valves in a vertical line, they deliver gas from the 
upper valve and liquid from the lower valve.  Five hundred (500) psig copper tubing fitted with a 
special adapter is used to connect the tank to the tubing system.  To connect the line to the 
container, a valve protection hood and the valve outlet cap are removed.  A wrench is used to 
connect the valving to the yoke.  A new gasket, which is supplied with the container is used each 
time a connection is made.  As part of the Process Safety Management Program leaks are then 
checked using ammonia vapor.  The appearance 
of white vapor indicates a chlorine leak.  A 
protective suit, gloves, and a self-contained breathing apparatus (SCBA) are worn by the operator 
and a chlorine tank repair kit are kept on hand in the unlikely event of a chlorine leak while 
changing tanks.  In the past five years, this facility has had no accidental releases of chlorine. 
 
    The City of Oswego Water Treatment Facility maintains a general accidental 
release prevention program and chemical specific prevention steps.  As a part of this program, a 
chlorine alarm system is in place at the facility.  The chlorine meter and alarm are located on the 
wall outside of the chlorine injection room.  The chlorine sensors are located in the injection 
room and the tank scale room.  In the event of a chlorine leak, a audio alarm will sound in the 
operator's control room which is staffed twenty four (24) hours a day, seven days a week.  The 
monitor is maintained and calibrated by an outside contractor. The calibration frequency is yearl 

as recommended by the manufacturer.  Literature and information on the alarm system is kept on 
file by the superintendent of the facility.  All employees are trained yearly on the chlorine alarm 
system.  An operator receiving an alarm is to call the Oswego Fire Department immediately.  In 
the event that the chlorine alarm system is inoperable, the chlorine tank scale room and the 
chlorine injection room will be checked by an operator hourly with a portable chlorine meter.  
The operator also carries a radio to communicate with another plant personnel should a leak be 
discovered. 
 
    The chlorine injection system itself operates under a vacuum produced by the injector 
mechanism.  Gas leaves the tank through a vacuum regulating valve.  A diaphragm senses 
vacuum on one side and atmospheric pressure on the other.  A spring loaded stem off the seat is 
displaced by force on the diaphragm.  Gas moves toward the flow control components and proper 
vacuum is maintained.  While under vacuum, g 
as enters the rotameter where it's flow is 
measured.  Gas flow rate is controlled by a v-notch orifice and either manual or automatic 
positioning of the v-grooved plug in it's ring.  A differential regulating valve is located after the 
orifice which maintains the proper vacuum across the v-notch.  A pressure-relief valve vents to 
the atmosphere if a malfunction occurs and pressure builds.  Gas is then dissolved in the water 
stream at the injector.  Check valves are in place and designed to close on injector shutdown.  
There are no lines carrying gas under pressure in this system.  Loss of vacuum for any reason 
causes the vacuum regulating valve to shut off the gas supply.   
 
    The facility also complies with the Occupational Safety and Health Process Safety 
Management rule.  Management believes that the training of it's employees and it's contractors is 
crucial to maintaining a safe environment and continuing it's accident-free record for the chlorine 
system.  Training of all employ 
ees consists of a general orientation of the chlorine system first.  
They are then instructed on the hazards and proper and safe handling of the chlorine system.  The 
following courses are administered to all employees and refreshed yearly: 
 
    General Safety Training 
    DEC Wastewater Operator Renewal Training 
    Hazard Communication Training 
    Confined Space Training 
    Respiratory Protection Program Training 
    Lock-out/Tag-out 
    Chlorine Tank Handling and Connections 
    Hearing Protection Program 
    Personal Protective Equipment Program 
 
A record is kept of the training and placed in the training files.  The record contains the 
employee or contractor name, title of course, date the course was held, name of the trainer, 
and results of any written, oral, or hands-on exam.    
 
    Accidents are also prevented by good administrative controls.  Standard Operating 
Procedures (SOPs) are kept on hand and are easily accessible to the workers.  Each operato 
r is 
trained in the applicable aspects of their job functions.  Those operators whose work is involved 
with any aspect of the chlorine injection system are thoroughly trained in those specific SOPs.  
Workers who need to be inside the chlorine tank scale  room or the chlorine injection room are  
provided chlorine specific training.     
 
    The City of Oswego Water Treatment Facility maintains an Emergency Management 
Program.  In the event of a chlorine leak,  the operator will first notify the other employees by 
sounding a general alarm and then determine the location and magnitude of the leak.  The 
magnitude is broken down to minor leaks; no yellowish gas is visibly present, and major leak; 
yellowish gas is visibly present.  The operator will call the Oswego Fire department immediately 
and then notify the other workers in the plant of the chlorine leak.  The operator will designate 
one location that is upwind from the chlorine leak for all personnel to assemble and remain until 
the f 
ire department informs the operator otherwise.  The superintendent will then be called and 
informed of the situation.  The Oswego Fire Department will be in charge of the scene until they 
depart.  The approximate response time is less than five minutes.  
 
    Each member of the fire department is trained to at least HazMat Level I.  Two 
members are trained to the Technician Level, and eleven members are trained to the Specialist 
Level.  The fire department has toured the plant to become familiar with what is on site, and 
develop different leak scenarios and practice emergency response measures.  In June of 1996, a 
HazMat drill with the Fulton Fire Department Haz-Mat Team was conducted.  The Haz-Mat 
Team was activated.  The scenario staged was that a tank while being changed, started leaking.  
A full decon was set up.  The entry personnel used the chlorine kit to stop the tank from leaking.  
A full critique was conducted, and everyone at the scene reviewed the site.  On March  18, 1997 

seven members of the Haz-Mat Team conducted a drill at the treatment plant.  This scenario was 
a leak in the feed line.  The crew followed SOPs to fix the problem.  In August and September 
1997, all four fire department shifts conducted a mock drill of a worker overcome by chlorine 
while in a confined space.  Monitoring equipment,  rigging, and harnesses were used in the entry.  
The fire department also has a chlorine tank simulator that they practice using an  "A" and a "B" 
chlorine tank repair kit on. 
 
    In the attached Risk Management Plan, toxic worst case and toxic alternative release 
scenarios were examined.  The scenarios were developed based on a two-thousand pound tank 
filled with 99.5 percent chlorine.  The quantity released was the full two thousand pounds at a 
release rate of two hundred pounds per minute for ten minutes.  The meteorological factors were 
an atmospheric stability class of "F" and a wind speed of 1.5 meters per second.  The topography 
is urban.  The rele 
ase is assumed to be at ground level.  The toxic endpoint is 0.0087mg/L 
(3ppm).  These airborne concentrations are the maximum airborne concentrations that most 
people can be exposed to for up to one hour without experiencing serious or irreversible effects 
or symptoms.  The calculated distance to endpoint is 1.3 miles. 
 
      The alternate release scenario for the chlorine injection system is one that is more likely 
to occur than the worst case scenario that reaches an end point off-site.  A chlorine leak caused 
by piping or valve failure is used in the alternative scenario.  A hole diameter of 1/4 inch on the 
piping or valve could theoretically occur.  The release rate for this scenario is 9 pounds per 
minute for 222.2 minutes.  The meteorological conditions were atmospheric stability class of "D" 
and a wind speed of 3.0 meters per second.  The topography is urban.  Again the toxic endpoint 
is 0.0087 mg/L (3 ppm).  The calculated distance to endpoint for the alternative scenario is  
0.10 
miles.  Methodology for determining distance to endpoints was done by referencing Risk 
Management Program Guidance for Wastewater Treatment Plants (40 CFR Part 68).  
 
    The chemical of concern at the Water Treatment Facility is chlorine.  Chlorine 
can be toxic if not handled properly, however, the City of Oswego has a reasonable program in 
place to minimize the potential risks to a chlorine gas release.  A training program combined 
with required recordkeeping, administrative controls, an effective emergency management 
program, a local HazMat team, and an alarm system all address and meet the needs of the 
applicable regulations as defined under 40 CFR 68 and 29 CFR 1910.119.  The Water Treatment 
Facility is currently evaluating improvements to their safety program.  They are investigating 
expanding the area that the chlorine sensors monitor, along with visual, as well as, audio alarms.  
They are also taking this opportunity to explore the possibility of improving  and expanding  
their 
training programs.  
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